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The Stille reaction /

Chi tiết về thư mục
Tác giả chính: Farina, Vittorio
Tác giả khác: Krishnamurthy, Venkat, Scott, William Johnston
Định dạng: Printed Book
Ngôn ngữ:English
Được phát hành: New York : J. Wiley, c1998.
Những chủ đề:
Truy cập trực tuyến:http://www.loc.gov/catdir/bios/wiley041/98039154.html
http://www.loc.gov/catdir/description/wiley032/98039154.html
http://www.loc.gov/catdir/toc/onix02/98039154.html
LEADER 03874pam a2200277 a 4500
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010 |a  98039154  
020 |a 0471312738 (pbk. : alk. paper) 
082 0 0 |a 547/.2  |2 21 
100 1 |a Farina, Vittorio. 
245 1 4 |a The Stille reaction /  |c Vittorio Farina and Venkat Krishnamurthy, William J. Scott. 
260 |a New York :  |b J. Wiley,  |c c1998. 
300 |a ix, 657 p. :  |b ill. ;  |c 23 cm. 
504 |a Includes bibliographical references (p. 633-652) and index. 
505 |a Mechanistic considerations, regiochemistry and stereochemistry. -- Scope and limitations: the electrophile. -- Alkenyl Halides. -- Aryl and Heterocyclic Halides. -- Acyl Chlorides. -- Allylic, Benzylic, and Propargylic Electrophiles. -- Alkenyl Sulfonates and Other Electrophiles. -- Aryland Heterocyclic Sulfonates and Other Derivatives. -- Miscellaneous Electrophiles. -- Scope and limitations: the stannane. -- Alkylstannanes. -- Alkenylstannes. -- Aryl and Heterocyclic Stannanes. -- Alkynylstannanes. -- Allylstannanes. -- Other Stannanes. -- Carbonylative couplings. -- Alkenyl Halides. -- Aryl and Heterocyclic Halides. -- Allylic and Benzylic Halides. -- Alkenyl Sulfonates. -- Aryl and Heterocyclic Sulfonates. -- Miscellaneous Substrates. -- Complex synthetic sequences involving tin-to-palladium (ii) metathesis steps. -- Side reactions. -- Homocoupling Reactions. -- Transfer of "Nontransferable" Ligands. -- Destannylation. -- Cine Substitution. -- Phosphorus-to-Palladium Aryl Migration. -- Electrophile Reduction. -- Product Isomerization. -- Miscellaneous Side Reactions. -- Comparison with other methods. -- Experimental conditions. -- The Stannane: Preparation and Handling. -- Alkenyl and Aryl Triflates. -- Choice of Nontransferable Ligands. -- Choice of Catalyst and Ligands. -- Choice of Solvent. -- Additives. -- Workup: Removal of Tin Halides. -- Experimental procedures. -- Trimethyl([3-(Cyclohexen-1-yl)-2-Propynyl)silane [Cross-Coupling of a Vinyl Halide with an Alkynylstannane Using Pd(PPh_3)_2Cl_2]. -- 4-tert Butyl-1-Vinylcyclohexene [Cross-Coupling of a Vinyl Triflate with a Vinylstannane Using Pd(PPh_3)_4 and LiCl]. -- 1-(4-Methoxyphenyl)-4-tert-Butylcyclohexene [Cross-Coupling of a Vinyl Triflate with an Arylstannane Using Pd_2(dba)_3 and AsPh_3]. -- 3-Methyl-2-(4-Tolyl)-2-Cyclopentenone [Cross-Coupling of an Unreactive Alkenyl Halide under "Modified" Conditions Using Pd(PhCN)_2Cl_2 AsPh_3, and Cul as Cocatalyst]. -- 1-(4-Nitrophenyl)-2-Propenone (Cross-Coupling of an Acid Chloride with an Arylstannane). -- 4-Allylacetophenone [Cross-Coupling of an Aryl Triflate under Mild Conditions using Tri(2-Furyl)Phosphine as Ligand. -- 8-(Trimethylstannyl)Quinoline (Preparation of an Arylstannane by Cross-Coupling and Aryl Triflate with Hexamethyldistannane). -- 4-(tert-Butyl-1-Vinylcyclohexen-1-Yl)-2-Propenone [Carbonylative Cross-Coupling of an Alkenyl Triflate with an Alkenylstannane using Pd(PPh_3)_4 and LiCl]. -- (E)-1-(4-Methoxphenyl)-3-Phenyl-2-Propenone [Carbonylative Cross-Coupling of an Aryl Triflate with an Alkenylstannane using Pd(dppf)Cl_2 and LiCl]. -- Tubular survey. -- Tables. -- References. 
650 0 |a Stille reaction. 
700 1 |a Krishnamurthy, Venkat. 
700 1 |a Scott, William Johnston, 
856 4 2 |u http://www.loc.gov/catdir/bios/wiley041/98039154.html 
856 4 2 |u http://www.loc.gov/catdir/description/wiley032/98039154.html 
856 4 |u http://www.loc.gov/catdir/toc/onix02/98039154.html 
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