Molecular symmetry /

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An accessible introduction to symmetry and spectroscopy, this text examines symmetry in nature and chemistry, point groups, the interaction of light with molecules, electronic spectra of transition metal complexes with a final chapter on symmetry and the spectra of complexes.

Bibliographic Details
Main Author: Willock, David J.
Format: Printed Book
Published: Chichester: John Wiley & Sons, 2009.
Subjects:
Molecular structure.
Molecular theory.
Symmetry (Physics).
Group theory.
Molecular spectroscopy.
Online Access:http://onlinelibrary.wiley.com/book/10.1002/9780470747414
Table of Contents:
  • Symmetry elements and operations
  • More symmetry operations and products of operations
  • The point groups used with molecules
  • Point group representations, matrices and basis sets
  • Reducible and irreducible representations
  • Applications in vibrational spectroscopy
  • Symmetry in chemical bonding
  • Appendix 1: H₂O models for identifying the results of symmetry operation products
  • Appendix 2: Assignment of chiral centre handedness using Cahn-Ingold-Prelog rules
  • Appendix 3: Model of a tetrahedron and the related cube
  • Appendix 4: Model of an octahedron
  • Appendix 5: Matrices and determinants
  • Appendix 6: The mathematical background to infrared selection rules
  • Appendix 7: The Franck-Condon principle
  • Appendix 8: Classical treatment of Stokes/anti-Stokes absorption
  • Appendix 9: The atomic orbitals of hydrogen
  • Appendix 10: The origin of chemical bonding+₂
  • Appendix 11: H₂O molecular orbital calculation in C₂[subscript v] symmetry
  • Appendix 12: Character tables.

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