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Asymmetric synthesis
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| Other Authors: | , |
| Format: | Printed Book |
| Published: |
Weinheim :
Wiley-VCH,
c2012
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| Edition: | 2nd, completely rev. ed. |
| Subjects: |
Table of Contents:
- Part I. Chiral auxiliaries in asymmetric synthesis. Introductory chapter / David A. Evans, Gunter Helmchen and Magnus Ruping ; Asymmetric epoxidation of pentadienols / Reinhard Brückner ; Asymmetric synthesis using sulfur-nitrogen reagents / Franklin A. Davis ; Asymmetric syntheses with SAMP-/RAMP-hydrazones / Dieter Enders and Wolfgang Bettray ; Asymmetric allylation reactions / Reinhard W. Hoffmann ; Carbohydrates as chiral auxiliaries / Horst Kunz ; The use of chiral oxazolines in early C-C bond forming reactions / Albert I. Meyers ; Asymmetric synthesis of amines and amino acids from amines / Shun-Ichi Murahashi and Yasushi Imada
- Part II. Metal-catalyzed asymmetric synthesis. Introductory chapter / Masakatsu Shibasaki and Shigeki Matsunaga ; Catalytic asymmetric sulfur ylide mediated epoxidation of carbonyl compounds / Varinder Aggarwal ; Asymmetric Baeyer-Villiger reactions / Carsten Bolm ; Planar chiral ligands based on [2.2]Paracyclophanes / Stefan Brase ; Asymmetric syntheses of 3-(trans-2-Nitrocyclopropyl)alanine and 3-(trans-2-Aminocyclopropyl)alanine / Armin de Meijere and Oleg V. Larionov ; Copper-Bis(oxazoline) catalyzed synthesis of b-Lactams - enantioselective reaction of alkynes with nitrones / David A. Evans, Florian Kleinbeck and Magnus Ruping ; Catalytic asymmetric conjugate addition reactions of organometallic reagents / Fernando Lopez and Ben L. Feringa ; Catalytic asymmetric synthesis of allylic alcohols via dynamic kinetic resolution / Hans-Joachim Gais ; Asymmetric cross-coupling reactions / Tamio Hayashi ; Asymmetric allylic substitutions / Gunter Helmchen ; Asymmetric homoaldol reactions / Dieter Hoppe ; Asymmetric vinylogous Mukaiyama Aldol reaction / Markus Kalesse and Jorma Hassfeld ; Chiral Lewis acid catalysis in aqueous media / Shu Kobayashi and Chikako Ogawa ; Asymmetric epoxidation of non-activated olefins / Kazuhiro Matsumoto and Tsutomu Katsuki ; Chiral carbonyl Lewis acid complexes in asymmetric syntheses / Keiji Maruoka and Takashi Ooi ; ZACA reaction: Zr-catalyzed asymmetric carboalumination of alkenes / Ei-ichi Negishi, Bo Liang, Tibor Novak and Ze Tan ; Bisoxazolines - a privileged ligand class for asymmetric catalysis / Andreas Pfaltz ; Enantioselective cycloaddition reactions catalyzed by hydrogen bonding / Viresh H. Rawal and Avinash N. Thadani ; Direct catalytic asymmetric Aldol-Tishchenko reaction / Masakatsu Shibasaki and Takashi Ohshima ; Asymmetric Heck and other palladium-catalyzed reactions / Lutz F. Tietze and Florian Lotz ; Asymmetric catalysis with chiral acid / Hisashi Yamamoto
- Part III. Biocatalysis and organocatalysis: asymmetric synthesis inspired by nature. Introductory chapter / Benjamin List ; Enantioselective photochemical reactions / Thorsten Bach ; Asymmetric catalysis via dynamic kinetic resolution / Jan-E. Bäckvall ; Catalytic asymmetric epoxidation of enones and related compounds / Albrecht Berkessel ; Kinetic investigations of the soai autocatalytic reaction / Donna G. Blackmond ; Planar-chiral heterocycles as enantioselective organocatalysts / Gregory C. Fu ; An organocatalytic approach to optically active six-membered rings / Karl Anker Jørgensen ; Non-linear effects in asymmetric catalysis / Henri B. Kagan ; Asymmetric organocatalysis / Steven V. Ley ; Directed evolution of enzymes for asymmetric syntheses / Manfred T. Reetz ; Asymmetric autocatalysis and its implications in the origin of chiral homogeneity of biomolecules / Kenso Soai and Tsuneomi Kawasaki ; Asymmetric synthesis using deoxyribose-5-phosphate aldolase / Chi-Huey Wong and William A. Greenberg
- Part IV. Asymmetric reactions in total synthesis. Introductory chapter / K. C. Nicolaou and Paul G. Bulger ; Ring rearrangement metathesis (RRM) in alkaloid synthesis / Nicole Holub and Siegfried Blechert ; Asymmetric synthesis of biaryls by the 'Lactone method' / Gerhard Bringmann, Tanja Gulder and Tobias A. M. Gulder ; Asymmetric synthesis of merrilactone A / Samuel J. Danishefsky ; Asymmetric synthesis of cyclic ketal and spiroaminal-containing natural products / Craig J. Forsyth ; Case studies at the metathesis/asymmetric synthesis interface / Alois Fürstner ; Asymmetric synthesis of amino acids by rhodium and ruthenium catalysis / Jean Pierre Genet ; Asymmetric syntheses of pheromones / Kenji Mori ; Total synthesis of polyketides using asymmetric Aldol reactions / Ian Paterson ; Asymmetric synthesis on the solid phase / Torben Le€mann and Herbert Waldmann
- Part V. Asymmetric synthesis in industry. Introductory chapter / Herbert Hugl ; Industrial application of enantioselective catalysis / Hans-Ulrich Blaser ; Crystallization-induced diastereoselection for the synthesis of aprepitant / J. Brands, P. Pye and K. Rossen ; Combinatorial methods in asymmetric synthesis / Stefan Dahmen ; Biocatalytic production of optically active amines / Klaus Ditrich ; The Monsanto L-Dopa process / William S. Knowles ; Asymmetric hydrogenation through metal-ligand bifunctional catalysis / Ryoji Noyori, Takeshi Ohkuma, Christian A. Sandoval and Kilian Muñiz ; Many ways are leading to Rome - today's variety of competing synthetic methods in industry / Andreas Job and Andreas Stolle.